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Palladium-mediated α-arylation of β-ketosulfones 2 with aryl iodides in the presence of LiTMP, ZnF 2 and RuPhos in THF afforded α-substituted β-arylketosulfones 1 with moderate to good yields. The reaction tolerated a range of aryl iodides with different functionalized substituents. Functionalized sulfonyl phenanthrenes 7 were prepared via the O-alkylation of skeleton 1 followed by photolytic...
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