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The effect of a cationic Langmuir-Blodgett (LB) multilayer of varying thickness on pK i of the weak acid 4-heptadecyl-7-hydroxy coumarin (HHC) located at the multilayer-phosphate buffer interface is investigated. The amphiphilic fluorescent dye is embedded in a neutral methyl arachidate (MA) monolayer that has been deposited atop of the LB-film during dipping. Such a system is considered as...
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