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The spin Hamiltonian (SH) parameters (g factors gx, gy and gz and the hyperfine structure constants Ax, Ay and Az) and local structure for the rhombic Rh4+ and Ir4+ centers in TiO2 (rutile) are theoretically studied from the perturbation formulas of these parameters for a low spin (S = 1/2) d5 ion under rhombically distorted octahedra. In the calculations, the ligand orbital and...
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