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Nine new compounds, including streptothiomycin A−E (1–5), two cyclopentenones (6, 7), one α‐pyrone (8), wailupemycin Q (20), along with sixteen known compounds were identified from a rhizosphere strain Streptomyces sp. DS‐27 derived from the marine cordgrass Spartina alterniflora under two different culture conditions. All of the structures were elucidated by extensive analysis of 1D/2D NMR and HR‐ESI‐MS...