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Hilfe für schwer Epoxidierbare: Terminale nicht‐konjugierte Olefine wie 1‐Octen sind „schwierige“ Substrate für die asymmetrische Epoxidierung. Von cis‐1,2‐Diaminocyclohexan (cis‐DACH) abgeleitete Ti‐Salalen‐Komplexe katalysieren diese anspruchsvolle Reaktion mit guten Ausbeuten und hoher Enantioselektivität (bis zu 95 % ee) und mit H2O2 als Oxidationsmittel. Röntgenstrukturanalysen der μ‐Oxo‐ und...
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