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New vanadyl(IV) complexes of tetradentate Schiff-base dianions containing one, two or three carbon atoms between the two iminato-nitrogen atoms are described. The compounds are either mononuclear or polymeric, as shown by the value of ν(V O), and depending upon the Schiff-base dianion. There is no evidence for electron delocalization along the polymeric chains. Some vanadium(III) complexes of bidentate...
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