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The effect of a small amount of ionic groups (interactions) on the morphology and deformation behavior of stoichiometric blends made of poly(styrene-co-styrenesulfonic acid) (SPS) and poly(methyl methacrylate-co-4-vinylpyridine) (MVP) was investigated by Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). FTIR data revealed that intermolecular ion–ion interactions...
The influence of ion content and ionomer morphology on deformation modes of poly(styrene-co-sodium methacrylate) ionomers has been examined. Dynamic mechanical thermal analysis indicates a morphology characteristic to amorphous ionomers: two separate loss peaks are observed, one associated with the glass transition of the multiplet-containing matrix phase and the higher temperature loss peak with...
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