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Three new copper(II) complexes of formulae [Cu(bpcam)(tcm)(H 2 O)]·2H 2 O (1), [Cu(bpcam)(tcm)(H 2 O)] (2) and [Cu(bpcam)(tcm)] n (3) [bpcam=bis(2-pyrimidylcarbonyl)amidate and tcm=tricyanomethanide] have been prepared and their structures determined by single crystal X-ray diffraction. Complexes 1 and 2 are mononuclear species where each copper atom is five-coordinated...
Five copper(II) complexes of formulas [Cu(bpcam)(CN)(H 2 O)] (1), [Cu(bpcam)(N 3 )(H 2 O)] 2 (2), [Cu(bpcam)(NCS)(H 2 O)] (3), [Cu(bpcam)(dca)(H 2 O)] 2 (4) and [Cu(bpca)(tcm)] n (5) [bpcam=bis(2-pyrimidylcarbonyl)amidate, bpca=bis(2-pyridylcarbonyl)amidate, dca=dicyanamide and tcm=tricyanomethanide] have been prepared and their structures...
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