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The diastereoselective 1,3‐dipolar cycloaddition between nitrones and enantiomerically pure 2,3‐dihydrothiazoles derived from L‐cysteine, with different oxidation states at the sulfur atom has been studied experimentally and computationally. The reaction takes place with complete regioselectivity and diastereofacial selectivity. On the other hand, the exo/endo selectivity showed a clear dependence...
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