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Reactions of the diazonium derivative of closo-decaborate anion with oxygen nucleophiles were studied. The reaction of [1-B 10 H 9 N 2 ] − with hydroxide ion gives the corresponding hydroxy derivative [1-B 10 H 9 OH] 2− in high yield. The reactions with OR (R=Me, Et, i-Pr, Ph) result in mixture of [1-B 10 H 9 OR] 2− and...
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