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Block copolymer CSO2500-β-CD-PLA3000 and CSO2500-β-CD-PLA5000 were synthesized via H-bonding-instructed double disulfide linkage and host–guest recognition between adamantane and β-cyclodextrin. Transmission electron microscopy and dynamic light scattering results further confirmed the formation of self-assembled micelles with an average size of 45 and 96 nm, and a polydispersity index of 0.178 and...
Redox-responsive micelles self-assembled from dynamic covalent block copolymers with double disulfide linkage in the backbone have been developed successfully. The amphiphilic block copolymers PEG–PLA associated with complementary H-bonding sequences can self-assemble into spherical micelles in aqueous media with sizes from 34nm to 107nm with different molar mass of PEG and PLA. Moreover, in vitro...
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