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The aim of this study is to highlight the impact of confinement effects in catalysis for reactants confined in small mesopores. Double bond isomerization of 1-hexene at 343K has been chosen as model reaction and mesostructured aluminosilicates of the MCM-41 type with the very same chemical composition (Si/Al=400±20) and varying pore sizes (2.3–9.3nm) were used as catalysts. Adsorption isotherms of...
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