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Goldkatalysierte Reaktionen …… in lebenden Mäusen werden von K. Tanaka et al. in der Zuschrift auf S. 3633 ff. beschrieben. Mit Glycoclustern modifizierte Goldkatalysatoren akkumulieren in spezifischen Organen in höheren Organismen und katalysieren dort chemische Umsetzungen. Dieser Ansatz könnte die Anwendung von metallorganischen Katalysatoren in der Therapie oder Diagnostik ermöglichen, indem sie...
Metal complex catalysis within biological systems is largely limited to cell and bacterial systems. In this work, a glycoalbumin–AuIII complex was designed and developed that enables organ‐specific, localized propargyl ester amidation with nearby proteins within live mice. The targeted reactivity can be imaged through the use of Cy7.5‐ and TAMRA‐linked propargyl ester based fluorescent probes. This...
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