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The electrochemical reactivity of the layered titanium hydrogeno phosphate Ti(HPO 4 ) 2 ·H 2 O versus lithium has been studied. Lithium intercalation occurs at ∼2.5V with low polarization, leading to a new lithiated Ti(III) phase, LiTi(HPO 4 ) 2 ·H 2 O. Ti(HPO 4 ) 2 ·H 2 O exhibits a reversible capacity of 80mAhg −1 in...
Polycrystalline samples of VOMoO 4 are prepared by a solid-state reaction method and their electrochemical properties are examined in the voltage window 0.005–3V versus lithium. The reaction mechanism of a VOMoO 4 electrode for Li insertion/extraction is followed by ex situ X-ray diffraction analysis. During initial discharge, a large capacity (1280mAhg −1 ) is observed and...
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