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The vibrational spectrum of the hormonal steriod 17β-estradiol has been assigned with the aid of pressure-tuning infrared (IR) and solution Raman spectroscopy. In addition, a pressure-tuning IR study of 17α-ethynylestradiol suggests that the 17α-ethynyl hydrogen is hydrogen bonded in the solid state. Related work on a series of organometallic estradiol derivatives indicates that the effect of substitution...
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