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In the present study, we demonstrated the effect of hydrogen bonding in the semiconducting behaviour of a small molecule used in organic field‐effect transistors (OFETs). For this study, the highly soluble dumbbell‐shaped molecule, Boc‐TATDPP based on a Boc‐protected thiophene‐diketopyrrolopyrrole (DPP) and triazatruxene (TAT) moieties was used. The two Boc groups of the molecule were removed by annealing...
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