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Selected area electron diffraction (SAED) and high resolution transmission electron microscopy (HRTEM) studies reveal that the crystal structure and microstructure of GdBaCo 2 O 5+δ are highly influenced by the oxygen stoichiometry. In addition to layered-type ordering of the Ba and Gd atoms along the c-direction of the structure and location of anion vacancies within the (GdO) ...
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