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Low-cost caprolactam (CPL) has been introduced into one-step anti-solvent process to fabricate efficient and stable planar perovskite solar cells (PSCs) for the first time. It is found that CPL as a Lewis base has the weak coordination ability to Pb(II), and this weak interaction will be easily broken by either anti-solvent dripping or annealing owing to the steric effect, thus leading to a compact...
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