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The reduction of NO with acetaldehyde on alumina-supported Pd, Mo, and Pd–Mo catalysts was studied. Two Mo loadings were used (8 and 20%), and the Pd–8% Mo/Al 2 O 3 catalyst was the most active for NO conversion. Temperature-programmed desorption and infrared measurements of adsorbed acetaldehyde indicated that acetate species are probably an important reaction intermediate. The presence...
The adsorption properties of ethanol, CO, and NO on Pd, Mo, and Pd–20Mo/Al 2 O 3 catalysts were studied using TPD and IR techniques as well as the reactions of NO+CO and ethanol+NO. The presence of Pd favored decomposition and dehydrogenation of ethanol, while Mo presented activity for oxidative dehydrogenation. The Pd–Mo catalyst showed better formation of N 2 on TPD of NO,...
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