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Self-assembly directed by dinuclear zinc(II) macrocyclic species with 4-aminopyridine, 4-dimethylaminopyridine and isonicotinonitrile produces four novel trans macrocycle-based complexes, namely three molecular stair elements and one one-dimensional (1D) polymeric stair. Controlled synthesis of the cis or trans isomers of 4-aminopyridine macrocyclic complexes (2a or 2b), where the same rigid macrocyclic...
Spontaneous resolution is achieved for the Δ and Λ enantiomeric pair of ruthenium(II) complexes obtained by conglomerate crystallization from alcohol–water solutions, which is uncommon for six-coordinate Ru(II) complexes. The enantiomerically pure crystals pack into the chiral P4 1 and P4 3 space groups, respectively. A ligand exchange reaction is found between phen and bpy ligands...
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