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Adsorption states and thermal desorption behavior of self-assembled monolayers (SAMs) of 2-thiophenethiol (TT) and 2-thiophenemethanethiol (TM) on Au(111) were investigated by X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM), and thermal desorption spectroscopy (TDS), and were compared with those of thiophene (TP) SAMs. The S 2p XP spectra of thiophenethiol SAMs showed a...
The formation of thin films by the adsorption of thiophene (TP) and 2,5-dimethylthiophene (DMTP) on Au(111) in 1 mM ethanol solutions was investigated by X-ray photoelectron spectroscopy (XPS) and scanning tunneling microscopy (STM). XPS and STM studies revealed that the adsorption of TP molecules on Au(111) gives rise to the formation of two-dimensional ordered self-assembled monolayers through chemisorption...
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