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Reactions of H 2 L [H 2 L=N,N′-bis(3-methoxysalicylidene)propane-1,2-diamine] and Ln(NO 3 ) 3 ·6H 2 O give rise to two different mononuclear 4f complexes, namely, {[(H 2 L)La(NO 3 ) 3 (MeOH)]·H 2 O} n (1) and [(H 2 L)Nd(NO 3 ) 3 ] (2). Further additions of Cu(Ac) 2 ·H 2 O to the...
A novel ligand 2′-(2″-nitro-3″,4″-methylenedioxyphenyl)imidazo[4′,5′-f][1,10]-phenanthroline (NMIP) and its complex [Ru(phen) 2 (NMIP)] 2+ have been synthesized and characterized by mass spectroscopy, 1 H NMR and cyclic voltammetry. Binding of the complex with calf thymus DNA (CT DNA) has been investigated by spectroscopic methods, viscosity and electrophoresis measurements...
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