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Isothermal and dynamic methodologies were used to study the thermal degradation of three [NTf2] anion-based ionic liquids (ILs): [C12MIM][NTf2], [N4441][NTf2] and [N8881][NTf2]. Although it is well known that thermal stability is clearly dominated by the coordination ability of the anion, results showed that the cation exerted a significant effect, this being greater in pyrolytic conditions than in...
Thermal degradation of five phosphonium cation-based ionic liquids ([P66614][BEHP], [P66614][(iC8)2PO2], [P66614][NTf2], [P44414][DBS] and [P4442][DEP]) was studied using dynamic methodology (25–600°C at 5, 10 and 20°C/min) in both inert (nitrogen) and reactive (oxygen) atmospheres. In addition, isothermal experiments (90min at 200, 225 and 250°C) were carried out with [P66614][(iC8)2PO2]. Results...
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