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The association behavior of an electron‐donating, bowl‐shaped, truxene‐based tetrathiafulvalene (truxTTF) with two corannulene‐based fullerene fragments, C32H12 and C38H14, is investigated in several solvents. Formation of 1:1 complexes is followed by absorption titrations and complemented by density functional theory (DFT) calculations. The binding constants are in the range log Ka=2.9–3.5. DFT calculations...
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