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Supersäuren aktivieren N‐SCF3‐Sulfenamide unter Bildung superelektrophiler diprotonierter Spezies für die Trifluormethylthiolierung aromatischer Amine. In der Zuschrift auf S. 175 ff. zeigen T. Billard, S. Thibaudeau et al., wie diese Methode für die Funktionalisierung komplexer Biomoleküle wie Alkaloide und Steroide verwendet werden kann.
Upon activation under superacid conditions, functionalized tailor‐made N‐SCF3 sulfenamides served as reagents for the trifluoromethylthiolation of aromatic amines. This method has a broad substrate scope and can be used for the late‐stage functionalization of complex molecules such as alkaloids or steroids. Mechanistic studies based on in situ low‐temperature NMR spectroscopy revealed the involvement...
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