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The reaction between aryl Grignard compounds and 5‐methoxy‐6‐nitroquinoline derivatives in THF was found to proceed in a chemodivergent mode that depended on the functional groups present in the heterocyclic ring. Thus, the reactions that started from carbostyril derivatives afforded 6‐(arylamino)carbostyrils as the major products, whereas those that started with 2‐alkoxyquinolines gave exclusively...
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