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Thermodynamic information about the metal-ligand interaction between Fe3+, Zn2+, Cu2+ and Sn2+, and a biodegradable ligand as MGDA is reported. The speciation scheme was obtained by means of potentiometric measurements and isothermal titration calorimetry (to determine enthalpy changes) in NaCl medium. The formation of the ML and MLOH species was evidenced for all the metal cations, and for Fe3+ also...
This work is focused on the determination of the thermodynamic parameters of interaction between a biodegradable complexone, as MGDA (methylglycinediacetic acid), towards the major constituents of natural fluids, such as H+, Na+, K+, Ca2+ and Mg2+. The determination of their thermodynamic parameters of interaction was performed by potentiometric and calorimetric measurements in different experimental...
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