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The electronic structure of hexagonal β-Nb 2 N and δ′-NbN, and cubic fcc δ-NbN, grown by magnetron sputtering, have been investigated by X-ray photoemission spectroscopy and ellipsometric measurements. The valence band (VB) energy distribution curves (EDC) of these nitrides significantly differ each from each other. The hybridized N2p–Nb4d bands of β-Nb 2 N originate a featureless...
Zr 1−x Al x N thin films, with 0≤x≤0.73, have been synthesized by magnetron sputtering. The phases and the electrical and optical properties have been investigated. For x≤0.43, the Zr 1−x Al x N films crystallize in cubic NaCl type of structure (B1 type), while at higher Al content, 0.43<x≤0.73, the films contain two phases: the cubic ZrN and the hexagonal AlN phases...
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