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The detailed structure of catalytic center of water oxidation, Mn4Ca-cluster, in photosystem II (PSII) has been reported recently. However, due to the radiation damage induced by X-ray and the complexity of the Mn4Ca-cluster, the assignment of the μ4-O5 atom coordinated by three Mn and one Ca2+ ions is still lack of essential evidences. In this article, we synthesized one Mn complex containing two...
In the field of photosynthetic water oxidation it has been under debate whether Tyrosine Z (Tyr Z ) acts as a hydrogen or an electron acceptor from water. In the former concept, direct contact of Tyr Z with substrate water has been assumed. However, there is no direct evidence for the interaction between Tyr Z and substrate water in active Photosystem II (PSII), instead...
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