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Reaction of 2-(naphthyl-1′-azo)-4-methylphenol with [Ir(PPh3)3Cl] in refluxing ethanol in the presence of a base (NEt3) affords an organoiridium complex of type [Ir(PPh3)2(L)(H)], where L represents the coordinated 2-(naphthyl-1′-azo)-4-methylphenolate ligand. A similar reaction carried out in toluene affords the [Ir(PPh3)2(L)(H)] complex along with a similar complex of type [Ir(PPh3)2(L)Cl]. Structures...
Reaction of picolinic acid (Hpic) with rhodium trichloride or iridium trichloride affords tris-picolinate complexes of the type [M(pic) 3 ] (M=Rh, Ir). The crystal structures of both complexes have been determined by X-ray diffraction. In both complexes, the picolinate ligands are coordinated to the metal center as bidentate N,O-donors forming five-membered chelate rings. There is one molecule...
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