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By simple modification of the functional groups on the donor unit, the thermally activated delayed fluorescence (TADF) properties of emitters can easily be manipulated. A series of deep blue to blue emissive TADF derivatives is developed, capable of deep‐blue emissions from 403 to 460 nm in toluene. Deep‐blue organic light‐emitting diodes (OLEDs) based on this series of TADF emitters are fabricated,...
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