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The side products formed in the TEMPO-mediated oxidation of glucose to glucaric acid were determined by GC. Next to glucaric acid, gluconic acid, the intermediate in the oxidation, the degradation products, oxalic acid, tartronic acid, meso- (erythraric) and dl-threaric (tartaric) acid were detected. Chiral GC determined the dl-tartaric acid to be non-racemic mixtures of l- and d-tartaric acids, with...
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