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Ga2S3 single crystals have been obtained by chemical vapor transport (CVT) in iodine vapors. The Ga2S3 compound was synthesized from Ga and S taken in stoichiometric quantities. The compound has been subjected to long term thermal annealing (TA) at the temperatures of 850 and 1070 K for 6 to 60 h in Zn vapors. After TA the natural surface of Ga2S3 single crystals contain a cover layer. The photoluminescence,...
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