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The physical properties of nanosized SiC particles are investigated as a function of the C/Si ratios. The synthesis by the laser pyrolysis process monitors the particle stoichiometry by the initial fluxes of the reactants (SiH 4 and C 2 H 2 ) and leads to Si- or C-rich batches. Spectroscopic methods such as EPR and Raman are used to probe the paramagnetic active electronic...
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