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[Ru(bipy)3]2+chemiluminescence: The mechanisms governing the selectivity of the luminescence of the [Ru(bipy)3]2+ complex (bipy=2,2′‐bipyridyl) were investigated using continuous flow EPR spectroscopy. The radical intermediates of substrates thought to evoke or quench the emission from this reagent were characterized in the light‐producing pathway.
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