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Only a few fused benzothiadizole (BTz) based conjugated polymers have been applied in organic field‐effect transistors (OFETs), and their performances were low, mainly due to the lack of available building blocks and in‐depth study of the relationship between structure and performance. Herein, we report two isomeric fused BTz‐based building blocks (M1 and M2) and their copolymers PBTzVBTz‐T and PBTzVBTz‐TT,...
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