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Hen‐egg‐white lysozyme (HEWL) is specifically cleaved at the Trp28–Val29 and Asn44–Arg45 peptide bonds in the presence of a Keggin‐type [Ce(α‐PW11O39)2]10− polyoxometalate (POM; 1) at pH 7.4 and 37 °C. The reactivity of 1 towards a range of dipeptides was also examined and the calculated reaction rates were comparable to those observed for the hydrolysis of HEWL. Experiments with α‐lactalbumin (α‐LA),...
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