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Calculation of X-ray absorption near-edge structure (XANES) has been used to investigate the chemical nature of zinc in thermal films formed on the surfaces of steel coupons by the additive zinc dialkyl dithiophosphate (ZDDP) in oil solution. Carbon K, oxygen K, and zinc L edge XANES spectra were used to characterize the thermal films and a model film formed by addition of cumene hydroperoxide (CHP)...
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