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A new complex of the title system ([2(H3O+)·18-crown-6]·2[BF4−]), which was induced by external magnetic field, has been prepared and characterized. When compared with other two members of the same system, the proton transfer induced by magnetic field from HBF4 to H2O has leads to the co-plane of six oxygen atoms in the crown and stronger HF and OF intermolecular interactions, which can be attributed...
OH, attacking via the hydroxylation and substituted dechlorination of the chlorinated aromatic ring, as well as by dehydration between the N atom and the acetoxyl. It could also be directly dechlorinated by ZVI reduction simultaneously. The reaction mechanism and promotional role of MF in the MF/ZVI/EDTA system were proposed. It is suggested that MF mainly alters the heterogeneous ZVI surface-bond...
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