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The crystallographic structure of the complex formed by β-cyclodextrin with 1,10-phenanthroline has been studied by X-ray diffraction. The result shows that the complex adopts an uncommon 2:3 stoichiometry in solid state, that is, every complex unit contains three 1,10-phenanthroline molecules and two β-cyclodextrin molecules, where two 1,10-phenanthroline molecules individually occupy two cyclodextrin...
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