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The chemical reactions and phases involved in the potential flux system of Li–Ca–N for the growth of bulk GaN crystals have been investigated under varying conditions. It is found that no preferential nitrification of Li or Ca by N 2 in Li–Ca melts at 500°C. Only the ternary compound LiCaN is identified in the Li–Ca–N system under the present experimental conditions. Static N 2 pressures...
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