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Benzotrifuroxan (BTF) as a powerful and hydrogen‐free explosive discolors under UV irradiation, but the process remains unclear. Herein, we comprehensively investigated the photochemical process and mechanism of BTF under UV irradiation. A pink color is observed in BTF after irradiation with 365‐nm light, while BTF becomes brown by 254‐nm light. Besides BTF, compound 1 is detected by ultrahigh‐performance...
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