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Halophilic reactions have been modeled theoretically by employing CBr 4 , Cl 3 CCN, Cl 3 CCOCl, CCl 4 and Cl 3 CF as substrates and Cl − as a nucleophile. It was found that the formation of the strong halogen bond is a necessary but not sufficient condition for the occurring of the halophilic reaction: the strong red-shifting halogen bond facilitates...
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