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Compounds of formula Pb(L 1 )(SCN) 2 .CH 3 CN (1) and Pb(L 3 )(SCN) 2 .0.5EtOH (2) (where L 1 is the lariat crown ether N,N'-bis(2-aminobenzyl)-1,10-diaza-15-crown-5 and L 3 is a Schiff-base macrobicyclic receptor derived from the condensation of L 1 with 2,6-diformylpyridine) were isolated and structurally characterised both in the solid...
Copper(II) complexes with a series of bibracchial lariat ethers are described. Independently of the nature of the counterion present (nitrate or perchlorate), the lariat ether N,N′-bis(2-aminobenzyl)-1,10-diaza-15-crown-5 (L 1 ) always forms mononuclear complexes, whereas the lariat ethers N,N′-bis(2-aminobenzyl)-4,13-diaza-18-crown-6 (L 2 ) and N,N′-bis(2-salicylaldiminobenzyl)-4,13-diaza-18-crown-6...
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