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For binary TiNi shape memory alloys, most research work has been devoted to the equiatomic or Ni-rich TiNi alloys, while very few systematical researches are reported on Ti-rich TiNi alloys. In this paper, the martensitic transformation and shape memory effect of Ti-rich Ti–49at.%Ni alloy were investigated by differential scanning calorimetry, optical microscopy, X-ray diffraction and testing of shape...
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