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The biosynthesis of (2S)-2-methyl-2-(4′-methyl-3′-pentenyl)-8-(3″-methyl-2-butenyl)-2H-1-benzopyran-6-carboxylic acid (gaudichaudianic acid), the major metabolite in leaves and roots of Piper gaudichaudianum Kunth (Piperaceae), has been investigated employing [1- 13 C]-d-glucose as precursor. The labelling pattern in the isolated gaudichaudianic acid was determined by quantitative 13 ...
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