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Cytochromes P450 can catalyze various regioselective and stereospecific oxidation reactions of non‐functionalized hydrocarbons. Here, we have designed a novel light‐driven platform for cofactor‐free, whole‐cell P450 photo‐biocatalysis using eosin Y (EY) as a photosensitizer. EY can easily enter into the cytoplasm of Escherichia coli and bind specifically to the heme domain of P450. The catalytic turnover...
Ein lichtgetriebenes System für die Kofaktor‐freie zelluläre Biokatalyse mit P450‐Cytochromen wird von C.‐H. Yun, K. J. Jeong, C. B. Park und Mitarbeitern in ihrer Zuschrift auf S. 983 ff. vorgestellt. Dieses neuartige Aktivierungssystem benötigt keine arbeitsintensiven und zeitraubenden Vorbehandlungen und kann auf jegliche Art von bakteriellen und humanen P450 angewendet werden. Statt teurer Kofaktoren...
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