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Herein, we introduce a variety of azopolyesters (azobenzene‐based polyesters) with remarkable intrinsic crystallinity and photoinduced reversible solid‐to‐liquid transition abilities from copolymerization of azobenzene‐based epoxides with cyclic anhydrides. The length of the soft alkyl side‐chain inlaid with azobenzenes and stereoregularity of main‐chain of azopolymers have tremendous effects on crystallization...
Herein, we introduce a variety of azopolyesters (azobenzene‐based polyesters) with remarkable intrinsic crystallinity and photoinduced reversible solid‐to‐liquid transition abilities from copolymerization of azobenzene‐based epoxides with cyclic anhydrides. The length of the soft alkyl side‐chain inlaid with azobenzenes and stereoregularity of main‐chain of azopolymers have tremendous effects on crystallization...