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The marine-derived fungus Trichoderma sp. TPU199 (cf. T. brevicompactum), originally isolated from a Palauan red alga, was found to produce unprecedented epipolythiodiketopiperazines, such as gliovirin and pretrichodermamide A. Long-term static fermentation of the strain induced the production of a new dipeptide, dithioaspergillazine A (1), together with aspergillazine A (2) and three anthraquinones...
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