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HeI and HeII photoelectron spectra of persistent free radical: 2,2,6,6-tetramethyl-4-(methylsulfonyloxy)piperidinyl-1-oxide (CH 3 SO 3 -TEMPO) have been measured. The analysis of the electronic structure is based on comparison with the spectra of related radicals and with DFT calculations. The electronic structure of the nitroxide group in the title radical seems unaffected by the...
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